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This paper provides an overview of spark-ignition engine unburned hydrocarbon emissions mechanisms, and then uses this framework to relate measured engine-out hydrocarbon emission levels to the processes within the engine from which they result. Typically, spark-ignition engine-out HC levels are 1.5 to 2 percent of the gasoline fuel flow into the engine; about half this amount is unburned fuel and half is partially reacted fuel components. The different mechanisms by which hydrocarbons in the gasoline escape burning during the normal engine combustion process are described and approximately quantified. The in-cylinder oxidation of these HC during the expansion and exhaust processes, the fraction which exit the cylinder, and the fraction oxidized in the exhaust port and manifold are also estimated.

CAI (Controlled Auto Ignition) combustion is already well known to be advantageous over conventional cycles in that it facilitates higher engine efficiency and has low emission characteristics. The CAI combustion process is mainly governed by in-cylinder RGF (Residual Gas Fraction), therefore achieving good control of in-cylinder RGF is essential in the development of CAI combustion engine. Usually, in-cylinder RGF controlled via low lift cam, short valve duration and negative valve overlap. More importantly on the other hand, accurate and instantaneous prediction of RGF must be done as a prerequisite to control. However, on-line prediction of RGF is not always practical due to the requirement of expensive fast response exhaust gas analyzers in the empirical case or otherwise due to theoretical models which are just too slow for application by means of simulation solving. In this paper, a newly enhanced theoretical model for predicting on-line in-cylinder RGF is introduced.

In this work, the operating strategy for diesel injection methods and a way to control the exhaust gas recirculation (EGR) rate under dual-fuel PCCI combustion with an appropriate ratio of low-reactivity fuel (propane) to achieve high combustion stability and low emissions is introduced. The standards of combustion stability were carbon monoxide (CO) emissions below 5,000 ppm and a CoV of the indicated mean effective pressure (IMEP) below 5 %. Additionally, the NOx emissions was controlled to not exceed 50 ppm, which is the standard of conventional diesel combustion, and PM emissions was kept below 0.2 FSN, which is a tenth of the conventional diesel value without a diesel particulate filter (DPF). The operating condition was a low speed and load condition (1,500 rpm/ near gIMEP of 0.55 MPa).

The alternative fuel jet propellant 8 (JP-8, NATO F-34) can be used as an auto-ignition source instead of diesel. Because it has a higher volatility than diesel, it provides a better air-fuel premixing condition than a conventional diesel engine, which can be attributed to a reduction in particulate matter (PM). In homogeneous charged compression ignition (HCCI) or dual-fuel premixed charge compression ignition (PCCI) combustion or reactivity controlled compression ignition (RCCI), nitrogen oxides (NOx) can also be reduced by supplying external exhaust gas recirculation (EGR). In this research, the diesel and JP-8 injection strategies under conventional condition and dual-fuel PCCI combustion with and without external EGR was conducted. Two tests of dual-fuel (JP-8 and propane) PCCI were conducted at a low engine speed and load (1,500 rpm/IMEP 0.55 MPa). The first test was performed by advancing the main injection timing from BTDC 5 to 35 CA to obtain the emissions characteristics.

The combustion process using two fuels with different reactivity, known as dual-fuel combustion or RCCI is mainly studied to reduce emissions while maintaining thermal efficiency compared to the conventional diesel combustion. Many studies have proven that dual-fuel combustion has a positive prospect in future combustion to achieve ultra-low engine-out emissions with high indicated thermal efficiency. However, a limitation on high-load expansion due to the higher maximum in-cylinder pressure rise rate (mPRR) is a main problem. Thus, it is important to establish the operating strategy and study the effect of in-cylinder flow motion with dual-fuel combustion to achieve a low mPRR and emissions while maintaining high-efficiency. In this research, the characteristics of gasoline-diesel dual-fuel combustion on different hardware were studied to verify the effect of the in-cylinder flow motion on dual-fuel combustion.

The role of 1D simulation tool is growing as the engine system is becoming more complex with the adoption of a variety of new technologies. For the reliability of the 1D simulation results, it is necessary to improve the accuracy and applicability of the combustion model implemented in the 1D simulation tool. Since the combustion process in SI engine is mainly determined by the turbulence, many models have been concentrating on the prediction of the evolution of in-cylinder turbulence intensity. In this study, two turbulence models which can resemble the turbulence intensity close to that of 3D CFD tool were utilized. The first model is dedicated to predicting the evolution of turbulence intensity during intake and compression strokes so that the turbulence intensity at the spark timing can be estimated properly. The second model is responsible for predicting the turbulence intensity of burned and unburned zone during the combustion process.

Various advanced combustion concepts, which can achieve higher thermal efficiency and emissions reduction, have been suggested as the emissions regulation gets stricter. Dual-fuel combustion that operates by using different fuels having both premixed and non-premixed combustion characteristics is one of the viable alternatives. In dual-fuel combustion, it is critical to understand air-fuel mixture distribution as it determines the ignition spot and following combustion phase. The fuel distribution in the engine is affected by various factors, such as chamber geometry, injection strategy or in-cylinder flow motion. Furthermore, among them, in-cylinder motion, usually described in terms of swirl or tumble motion, is mostly affected by in-cylinder port geometry. In this paper, 3-dimensional Computational Fluid Dynamics (CFD) was used to investigate the effect of in-cylinder flow motion in dual-fuel combustion. Two head and port geometries were used in the simulations.

Novel Diesel combustion concepts such as premixed charge compression ignition (PCCI) and reactivity controlled compression ignition (RCCI) promise lower NOx and PM emissions than those of conventional Diesel combustion. RCCI, which can be implemented using low-reactivity fuels such as gasoline or gases and high-reactivity fuels such as Diesel, has the potential to achieve extremely low emissions and improved thermal efficiency. However, to achieve RCCI combustion, a higher boost pressure than that of a conventional engine is required because a high EGR rate and a lean mixture are necessary to achieve a low combustion temperature. However, higher boost pressures can cause damage to intake systems. In this research, the addition of gaseous fuel to a CI engine is investigated to reduce engine emissions, mainly NOx and PM emissions, with the same IMEP level. Two different methods were evaluated.